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Title: | First example of antimoniated Schiff bases: Hypervalent Sb <- N(sp(2)) bonds |
Authors: | Sharma, P Perez, D Vazquez, J Toscano, A Gutierrez, R |
Issue Date: | 2007 |
Abstract: | The first example of antimoniated Schiff bases viz. 1-[2-(bis-(2-[(1-R-p-tolylethylimino)methyl]phenyl)stibanyl)benz-E-ilidene]-(1-R-p-tolylethyl)amine (4) and tris[(R)-2-benzyliden-2-yl-amino)butan-1-ol]stibine (2) containing imino groups at the ortho position of aryl ring have been synthesized and characterized. The compounds were obtained by the reaction of tris(o-formylphenyl)stibine with R-4-dimethyl benzyl amine or (R)-2-aminobutan-1-ol, respectively. These chiral antimony based Schiff bases were characterized by IR, mass, H-1, C-13, NMR spectroscopy. The X-ray crystal structures of these two Schiff bases show hypervalent interactions between antimony and sp(2) nitrogen atoms. Additionally compound 2 shows intramolecular Sb-O interaction also giving eight-coordination of antimony, both of these observations are uncommon in literature. These two compounds 1 and 2 show helicoidal chirality, which is a very new concept in antimony chemistry. (c) 2006 Elsevier B.V. All rights reserved. |
URI: | http://hdl.handle.net/11154/1186 |
ISSN: | 1387-7003 |
Appears in Collections: | Ciencias
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