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Title: | Synthesis, characterization and cyclohexene hydrogenation activity of high surface area molybdenum disulfide catalysts |
Authors: | Soto-Puente, M Del Valle, M Flores-Aquino, E Avalos-Borja, M Fuentes, S Cruz-Reyes, J |
Issue Date: | 2007 |
Abstract: | An ammonium tetrathiomolybdate (ATTM) catalyst precursor is synthesized and then thermally decomposed at different temperatures in N-2 or H-2 atmosphere. Characterization of the resulting compounds by powder X-ray diffraction (XRD) and surface area analysis indicates the formation of MoS2-2H with a surface area of 5-9 m(2)/g. When ATTM is treated with cetyltrimethylammonium chloride and then decomposed in N-2 at 723 K, the resulting material has a surface area nearing 200 m(2)/g. If treatment also includes hydrazine, the surface area of the resulting MoS2-2H reaches 215 m(2)/g. Analysis by XRD and electron microscopy shows a noticeable dispersion in the layers of the resulting MoS2. The catalytic activity of the materials is tested in a batch reactor for cyclohexene hydrogenation, where the highest activity sulfides are those obtained by thermal decomposition of the chemically treated precursors in N-2. |
URI: | http://hdl.handle.net/11154/1196 |
ISSN: | 1011-372X |
Appears in Collections: | Ciencias
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