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Title: | Asymmetric synthesis of cyclopropanes by reaction of (2E, SS)-(+)-4,4-diethoxy-2-[(4-methylphenyl)sulfinyl]but-2-enenitrile and 2-methoxyfuran |
Authors: | Cruz, DC Yuste, F Diaz, E Ortiz, B Walls, F Ruano, JLG Sánchez-Obregon, R |
Issue Date: | 2005 |
Abstract: | The reaction of 2-methoxyfuran with the 2-sulfinylacrylonitrile 1 provides a route to the asymmetric synthesis of cyclopropanes. Problems associated with the separation of the two formed diastereoisomers and the epimerization observed in desulfinylation reactions are described. |
URI: | http://hdl.handle.net/11154/1385 |
ISSN: | 1424-6376 |
Appears in Collections: | Ciencias
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