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Please use this identifier to cite or link to this item:
http://hdl.handle.net/11154/1503
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| Title: | Cyclopalladated complexes derivates of phenylhydrazones and their use as catalysts in ethylene polymerization |
| Authors: | Perez, MA
Quijada, R
Ortega-Jimenez, F
Alvarez-Toledano, C |
| Issue Date: | 2005 |
| Abstract: | New cyclopalladated complexes (Pd-A, Pd-B, Pd-C) were used as catalysts in ethylene polymerization. All of them show good activity, especially at a temperature of 80 degreesC. The molecular weight and molecular weight distribution obtained correspond to single-site catalysts, producing polymers with narrow molecular weight distribution. The melting points correspond to linear polyethylene. UV-visible spectroscopy studies were used to determine possible polymerization mechanisms. (C) 2004 Elsevier B.V All rights reserved. |
| URI: | http://hdl.handle.net/11154/1503 |
| ISSN: | 1381-1169 |
| Appears in Collections: | Ciencias
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