|
Repositorio Atenea de la Facultad de Ciencias, UNAM >
Repositorio Ciencias >
FACULTAD DE CIENCIAS >
Ciencias >
Please use this identifier to cite or link to this item:
http://hdl.handle.net/11154/221
|
| Title: | On the selective methylation of benzoyl and furoylthiocarbamates |
| Authors: | Plutin, AM
Suarez, M
Machado, T
Alvarez, A
Martínez, R
Duque, J
Martínez-Alvarez, R
Martin, N
Rodríguez, A |
| Issue Date: | 2010 |
| Abstract: | The methylation reaction of alkyl N-acylthiocarbamates in DMF with dimethyl sulfate in the presence of potassium carbonate takes place with high selectivity affording the S-methylated derivative as the principal reaction product. No isomeric reaction products derived from the N- or the O-methylation were isolable. The new carbonimidothioates 3a-g synthesised were fully characterized by spectroscopic methods. The experimental findings are supported by X-ray and theoretical studies at the B3LYP/6-311G(d.p) level. |
| URI: | http://hdlhandlenet/123456789/170 |
| ISSN: | 1551-7004 |
| Appears in Collections: | Ciencias
|
Files in This Item:
There are no files associated with this item.
|
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.
|
