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http://hdl.handle.net/11154/912
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Title: | A formal synthesis of (+)-(S)-kurasoin B |
Authors: | Yuste, F Mastranzo, VM Ortiz, B Ruano, JLG Sánchez-Obregon, R |
Issue Date: | 2009 |
Abstract: | A new diastereoselective synthesis of (S)-1-[(S)-oxiran-2-yl]-2-phenylethanone (10), a key intermediate in the synthesis of kurasoin B (2), has been accomplished in seven steps in an overall yield of 32%. The key synthetic step in the process is the diastereoselective reduction of the beta-keto sulfoxide 6 derived from (S)-phenyllactic acid. |
URI: | http://hdl.handle.net/11154/912 |
ISSN: | 1424-6376 |
Appears in Collections: | Ciencias
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