Browsing by Subject "hypervalent antimony"

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First example of antimoniated Schiff bases: Hypervalent Sb <- N(sp(2)) bonds

Sharma, P; Perez, D; Vazquez, J; Toscano, A; Gutierrez, R (2007)

The first example of antimoniated Schiff bases viz. 1-[2-(bis-(2-[(1-R-p-tolylethylimino)methyl]phenyl)stibanyl)benz-E-ilidene]-(1-R-p-tolylethyl)amine (4) and tris[(R)-2-benzyliden-2-yl-amino)butan-1-ol]stibine (2) ...
Formation of (vinyl-ferrocenyl)stibines involving beta-elimination: Hypervalent Sb-N bonding

Vazquez, J; Sharma, P; Cabrera, A; Toscano, A; Perez, J; Gutierrez, R; Hernández, S (2007)

Unusual syntheses of vinyl substituted ferrocenylstibines viz. diphenyl(2-vinylferrocenyl) stibine (2) and iodo-(N, N-dimethylamino-ethylferrocenyl)(2-vinylferrocenyl)stibine (4) involving beta-elimination, are reported. ...

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