| dc.contributor.author |
Perez, MA |
|
| dc.contributor.author |
Quijada, R |
|
| dc.contributor.author |
Ortega-Jimenez, F |
|
| dc.contributor.author |
Alvarez-Toledano, C |
|
| dc.date.accessioned |
2011-01-22T10:27:16Z |
|
| dc.date.available |
2011-01-22T10:27:16Z |
|
| dc.date.issued |
2005 |
|
| dc.identifier.issn |
1381-1169 |
|
| dc.identifier.uri |
http://hdl.handle.net/11154/1503 |
|
| dc.description.abstract |
New cyclopalladated complexes (Pd-A, Pd-B, Pd-C) were used as catalysts in ethylene polymerization. All of them show good activity, especially at a temperature of 80 degreesC. The molecular weight and molecular weight distribution obtained correspond to single-site catalysts, producing polymers with narrow molecular weight distribution. The melting points correspond to linear polyethylene. UV-visible spectroscopy studies were used to determine possible polymerization mechanisms. (C) 2004 Elsevier B.V All rights reserved. |
en_US |
| dc.language.iso |
en |
en_US |
| dc.title |
Cyclopalladated complexes derivates of phenylhydrazones and their use as catalysts in ethylene polymerization |
en_US |
| dc.type |
Article |
en_US |
| dc.identifier.idprometeo |
1686 |
|
| dc.identifier.doi |
10.1016/j.molcata.2004.08.013 |
|
| dc.source.novolpages |
226(2):291-295 |
|
| dc.subject.wos |
Chemistry, Physical |
|
| dc.description.index |
WoS: SCI, SSCI o AHCI |
|
| dc.subject.keywords |
palladium complex |
|
| dc.subject.keywords |
non-metallocene |
|
| dc.subject.keywords |
catalyst |
|
| dc.subject.keywords |
ethylene |
|
| dc.subject.keywords |
polymerization |
|
| dc.relation.journal |
Journal of Molecular Catalysis A-Chemical |
|