dc.contributor.author | Klimova, EI | |
dc.contributor.author | Klimova, T | |
dc.contributor.author | Alamo, MF | |
dc.contributor.author | Iturbide, DM | |
dc.contributor.author | García, MM | |
dc.date.accessioned | 2011-01-21T10:35:26Z | |
dc.date.available | 2011-01-21T10:35:26Z | |
dc.date.issued | 2009 | |
dc.identifier.issn | 0022-152X | |
dc.identifier.uri | http://hdlhandlenet/123456789/258 | |
dc.description.abstract | The reactions of 1-amino-2,3-diferrocenylcyclopropenylium tetrafluoroborate (5a-c) or 2,3-diferrocenyl-l-methylthiocyclopropenylium iodide with sodium azide afford 5-methylthino-4,6-diferrocenyl-1,2,3-triazines (7a-c) or 5-methylthio-4,6-diferrocenyl- and 4-methylthio-5,6-diferrocenyl-1,2,3-triazines (8a and 8b), respectively. Their structures were established using spectroscopic methods and that of compound 8a was confirmed using X-ray diffraction analysis. Triazines 5a-c react with alkyl iodides to yield N(2)- and N-alkyl-C(5)-derivatives. Their alkaline hydrolysis results in 2-methyl-4,6-diferrocenyl-2,5dihydro-1,2,3-triazin-5-one (16) and 4,6-diferrocenyl-5-hydroxy-1,2,3-triazine (17). | en_US |
dc.language.iso | en | en_US |
dc.title | Synthesis, Structure, and Some Chemical Properties of Diferrocenyl-1,2,3-triazines | en_US |
dc.type | Article | en_US |
dc.identifier.idprometeo | 71 | |
dc.identifier.doi | 10.1002/jhet.93 | |
dc.source.novolpages | 46(3):477-483 | |
dc.subject.wos | Chemistry, Organic | |
dc.description.index | WoS: SCI, SSCI o AHCI | |
dc.relation.journal | Journal of Heterocyclic Chemistry |
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