dc.contributor.author |
Alvarez-Toledano, C |
|
dc.contributor.author |
Delgado, E |
|
dc.contributor.author |
Donnadieu, B |
|
dc.contributor.author |
Martin, G |
|
dc.contributor.author |
Zamora, F |
|
dc.contributor.author |
Hernández, E |
|
dc.date.accessioned |
2011-01-22T10:27:21Z |
|
dc.date.available |
2011-01-22T10:27:21Z |
|
dc.date.issued |
2003 |
|
dc.identifier.issn |
0020-1693 |
|
dc.identifier.uri |
http://hdl.handle.net/11154/1724 |
|
dc.description.abstract |
The unsaturated derivatives [Fe-2(CO)(6)(mu-S2C=CHC(O)C6H4X)] (X = F, OMe) have been isolated by reaction of [(HS)(2)C = CHC(O)C6H4X] (X = F, OMe) with Fe-3(CO)(12) in dried THF. Addition of Fe-2(CO)(9) to a solution of [Fe-2(CO)(6)(mu-S2C = CHC(O)C6H4OMe)] affords [Fe(CO)(4){mu-(OMe)C6H4C(O)CH = C(S)(2)Fe-2(CO)(6)}]. The new compounds have been characterised by analytical and spectroscopic data and the crystal structure of [Fe-2(CO)(6)(mu-S2C = CHC(O)C6H4F)] has been solved by X-ray diffraction. (C) 2003 Elsevier Science B.V. All rights reserved. |
en_US |
dc.language.iso |
en |
en_US |
dc.title |
Reactivity of Fe-3(CO)(12) towards thiols containing an alpha,beta-unsaturated ketone system |
en_US |
dc.type |
Article |
en_US |
dc.identifier.idprometeo |
1972 |
|
dc.identifier.doi |
10.1016/S0020-1693(03)00194-4 |
|
dc.source.novolpages |
351:119-122 |
|
dc.subject.wos |
Chemistry, Inorganic & Nuclear |
|
dc.description.index |
WoS: SCI, SSCI o AHCI |
|
dc.subject.keywords |
iron carbonyl |
|
dc.subject.keywords |
thiolate |
|
dc.subject.keywords |
alpha,beta-unsaturated ketone |
|
dc.relation.journal |
Inorganica Chimica Acta |
|