A stereodivergent approach to syn- and anti-beta-hydroxy-gamma-amino acids. Enantioselective synthesis of N-Boc-statine and N-Boc-3-epistatine mediated by sulfoxides
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A stereodivergent approach to syn- and anti-beta-hydroxy-gamma-amino acids. Enantioselective synthesis of N-Boc-statine and N-Boc-3-epistatine mediated by sulfoxides
Asymmetric syntheses of the syn- and anti-stereoisomers of N-Boc statine, based on the stereodivergent reduction of a single sulfoxide 5, derived from N-Boc-L-leucine, are reported. (C) 2003 Elsevier Science Ltd. All rights reserved.