dc.contributor.author | Burillo, C | |
dc.contributor.author | Banos, L | |
dc.contributor.author | Valera, M | |
dc.contributor.author | López, D | |
dc.date.accessioned | 2011-01-22T10:26:59Z | |
dc.date.available | 2011-01-22T10:26:59Z | |
dc.date.issued | 2001 | |
dc.identifier.issn | 1385-772X | |
dc.identifier.uri | http://hdl.handle.net/11154/1968 | |
dc.description.abstract | The synthetic route chosen to prepare the monomer 1-mono-p-phenylbenzoate of glycerol (1PHBGly) involved the synthesis of 1,2-O-isopropyliden-3-p-phenylbenzoate of glycerol followed by its hydrolysis with acid. This monomer has the phenylbenzoate mesogenic group attached. 1-mono-p-phenylbenzoate of glycerol was polyesterificated by melt bulk polycondensation with hexanediol (HD) and terephthaloyl chloride (TPHCl) in order to have a soluble polymer. Products were characterized by FTIR,H-1-NMR, DSC, powder X-ray diffraction, polarizing microscopy. In the case of the polymer. inherent viscosity was also determined. An amorphous copolymer. 1PHBGly/HD/TPHCl, was obtained. On the other hand, the 1,2-O-isopropyliden-3-p-phenylbenzoate of glycerol, the monomer (1PHBGly) and its copolymer did not form mesophases by heating. | en_US |
dc.language.iso | en | en_US |
dc.title | Synthesis and polyesterification of 1-mono-p-phenylbenzoate of glycerol | en_US |
dc.type | Article | en_US |
dc.identifier.idprometeo | 2359 | |
dc.source.novolpages | 4(1):45-51 | |
dc.subject.wos | Polymer Science | |
dc.description.index | WoS: SCI, SSCI o AHCI | |
dc.subject.keywords | 1-mono-p-phenylbenzoate of glycerol | |
dc.subject.keywords | copolyester | |
dc.subject.keywords | mesogenic group | |
dc.relation.journal | Designed Monomers and Polymers |
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