Abstract:
Synthesis of novel mono- and dinuclear complexes of Fe(0) are reported displaying both coordination and organometallic bonds. 5-11 were prepared by allowing the new ligands 1-4 to react with Fe-2(CO)(9). The structures of the complexes were determined by spectroscopic methods (IR, MS, HR-MS, H-1 and C-13 NMR) and confirmed by single-crystal X-ray analysis.