| dc.contributor.author |
Arroyo, M |
|
| dc.contributor.author |
Bernes, S |
|
| dc.contributor.author |
Brianso, JL |
|
| dc.contributor.author |
Mayoral, E |
|
| dc.contributor.author |
Richards, RL |
|
| dc.contributor.author |
Rius, J |
|
| dc.contributor.author |
Torrens, H |
|
| dc.date.accessioned |
2011-01-22T10:27:33Z |
|
| dc.date.available |
2011-01-22T10:27:33Z |
|
| dc.date.issued |
2000 |
|
| dc.identifier.issn |
0022-328X |
|
| dc.identifier.uri |
http://hdl.handle.net/11154/2098 |
|
| dc.description.abstract |
Thermolysis of [Os(SR)(3)(PMe2Ph)(2)] (R = C6F5 (1a) or C6HF4-4 (1b)) in refluxing toluene affords [Os(SC6F5)(2)(o-S2C6F4)(PMe2Ph)] (2a), [Os(SC6HF4)(2)(o-S2C6HF3)(PMe2Ph)] (2b), and [Os(C6F5)(2)(o-S2C6F4)(PMe2Ph)(2)] (3a) through processes involving C-F and C-S bond cleavage as well as rearrangement of C-S bonds. The single-crystal diffraction structures of la, 2a and 3a have been determined. In the solid state compound 1a shows a C-F --> Os interaction. (C) 2000 Elsevier Science S.A. All rights reserved. |
en_US |
| dc.language.iso |
en |
en_US |
| dc.title |
C-F bond activation in polyfluorobenzothiolate compounds of Os(III). X-ray structures of [Os(SC6F4(F-2))(SC6F5)(2)(PMe2Ph)(2)], [Os(SC6F5)(2)(o-S2C6F4)(PMe2Ph)] and [Os(C6F5)(2)(o-S2C6F4)(PMe2Ph)(2)] |
en_US |
| dc.type |
Article |
en_US |
| dc.identifier.idprometeo |
2535 |
|
| dc.source.novolpages |
599(2):170-177 |
|
| dc.subject.wos |
Chemistry, Inorganic & Nuclear |
|
| dc.subject.wos |
Chemistry, Organic |
|
| dc.description.index |
WoS: SCI, SSCI o AHCI |
|
| dc.subject.keywords |
C-F bond activation |
|
| dc.subject.keywords |
polyfluorobenzothiolate |
|
| dc.subject.keywords |
osmium |
|
| dc.subject.keywords |
thermolysis |
|
| dc.relation.journal |
Journal of Organometallic Chemistry |
|