dc.contributor.author |
Granifo, J |
|
dc.contributor.author |
Vargas, M |
|
dc.contributor.author |
Garland, MT |
|
dc.contributor.author |
Ibanez, A |
|
dc.contributor.author |
Gavino, R |
|
dc.contributor.author |
Baggio, R |
|
dc.date.accessioned |
2011-01-22T10:25:57Z |
|
dc.date.available |
2011-01-22T10:25:57Z |
|
dc.date.issued |
2008 |
|
dc.identifier.issn |
1387-7003 |
|
dc.identifier.uri |
http://hdl.handle.net/11154/2217 |
|
dc.description.abstract |
The new terpyridyl ligand 4'-phenyl-3,2':6',3 ''-terpyridine (L) reacts with Zn(acac)(2) to produce the dizinc complex [Zn-2(mu-L)(acac)(4)] center dot H2O (1) (acac = acetylacetonato). The analysis of the crystal structure of this zero-dimensional (0D) complex shows the existence of two Zn(acac)(2) centers bridged symmetrically by one mu-L ligand. The key role played by the acac and L ligands and the guest water molecule allows the generation of a series of intermolecular hydrogen bonds of the O-H/O, C-H/O and C-H/pi type which give raise to a 3D supramolecular array. The observed C-H/pi interactions are so widespread that all the pi-rings present in the structure, viz., those belonging to the L ligand as well as the acetylacetonato chelate rings, participate as hydrogen bond acceptors. (C) 2008 Elsevier B.V. All rights reserved. |
en_US |
dc.language.iso |
en |
en_US |
dc.title |
The novel ligand 4 '-phenyl-3,2 ':6 ',3 ''-terpyridine (L) and the supramolecular structure of the dinuclear complex [Zn-2(mu-L)(acac)(4)] center dot H2O (acac = acetylacetonato) |
en_US |
dc.type |
Article |
en_US |
dc.identifier.idprometeo |
720 |
|
dc.identifier.doi |
10.1016/j.inoche.2008.09.009 |
|
dc.source.novolpages |
11(11):1388-1391 |
|
dc.subject.wos |
Chemistry, Inorganic & Nuclear |
|
dc.description.index |
WoS: SCI, SSCI o AHCI |
|
dc.subject.keywords |
Polypyridine complexes |
|
dc.subject.keywords |
Supramolecular structure |
|
dc.subject.keywords |
C-H/pi interaction |
|
dc.subject.keywords |
C-H/O interaction |
|
dc.subject.keywords |
Hydrogen bond |
|
dc.relation.journal |
Inorganic Chemistry Communications |
|