On the selective methylation of benzoyl and furoylthiocarbamates

dc.contributor.author	Plutin, AM
dc.contributor.author	Suarez, M
dc.contributor.author	Machado, T
dc.contributor.author	Alvarez, A
dc.contributor.author	Martínez, R
dc.contributor.author	Duque, J
dc.contributor.author	Martínez-Alvarez, R
dc.contributor.author	Martin, N
dc.contributor.author	Rodríguez, A
dc.date.accessioned	2011-01-21T09:04:21Z
dc.date.available	2011-01-21T09:04:21Z
dc.date.issued	2010
dc.identifier.issn	1551-7004
dc.identifier.uri	http://hdlhandlenet/123456789/170
dc.description.abstract	The methylation reaction of alkyl N-acylthiocarbamates in DMF with dimethyl sulfate in the presence of potassium carbonate takes place with high selectivity affording the S-methylated derivative as the principal reaction product. No isomeric reaction products derived from the N- or the O-methylation were isolable. The new carbonimidothioates 3a-g synthesised were fully characterized by spectroscopic methods. The experimental findings are supported by X-ray and theoretical studies at the B3LYP/6-311G(d.p) level.	en_US
dc.language.iso	en	en_US
dc.title	On the selective methylation of benzoyl and furoylthiocarbamates	en_US
dc.type	Article	en_US
dc.identifier.idprometeo	57
dc.source.novolpages	:276-290
dc.subject.wos	Chemistry, Organic
dc.description.index	WoS: SCI, SSCI o AHCI
dc.subject.keywords	Methylation
dc.subject.keywords	polydentate system
dc.subject.keywords	structural study
dc.subject.keywords	X ray diffraction
dc.subject.keywords	thiocarbamic ester
dc.relation.journal	Arkivoc