dc.contributor.author |
Ferrari, R |
|
dc.contributor.author |
Bernes, S |
|
dc.contributor.author |
de Barbarin, CR |
|
dc.contributor.author |
Mendoza-Diaz, G |
|
dc.contributor.author |
Gasque, L |
|
dc.date.accessioned |
2011-01-22T10:27:23Z |
|
dc.date.available |
2011-01-22T10:27:23Z |
|
dc.date.issued |
2002 |
|
dc.identifier.issn |
0020-1693 |
|
dc.identifier.uri |
http://hdl.handle.net/11154/2502 |
|
dc.description.abstract |
Glycylglutamic acid (GEH(2)) is a peptide usually present in calcium binding sites. The interaction between the peptide and the cations Ca2+ Pb2+, Cd2+, and Zn in aqueous solution and in the solid state is described. Six compounds were isolated with different protonation states of the ligand. Potentiometric equilibrium studies, C-13 and Cd-111 solid state CP MAS NMR and IR spectroscopy were performed. Two crystal structures are reported: [Pb(GEH)(H2O)](1/2)]ClO4 and [Cd(GEH)(2)].3H(2)O. Both constitute 3D polymers, where only carboxylate groups are coordinated to the cations. The crystalline lead compound shows a hemidirected coordination sphere due to its stereochemically active lone pair. In deprotonated derivatives, it is possible to assign a metal-amino interaction to a far IR signal (340-370 cm(-1)). (C) 2002 Elsevier Science B.V. All rights reserved. |
en_US |
dc.language.iso |
en |
en_US |
dc.title |
Interaction between Glyglu and Ca2+, Pb2+, Cd2+ and Zn2+ in solid state and aqueous solution. Crystal structures of poly[aqua-1,2-kappa-O-di[lead(glygluH)]bis(perchlorate)] and poly[bisglycylglutamic-cadmium(II) tetrahydrate] |
en_US |
dc.type |
Article |
en_US |
dc.identifier.idprometeo |
2108 |
|
dc.source.novolpages |
339:193-201 |
|
dc.subject.wos |
Chemistry, Inorganic & Nuclear |
|
dc.description.index |
WoS: SCI, SSCI o AHCI |
|
dc.subject.keywords |
glycylglutamic acid |
|
dc.subject.keywords |
cations |
|
dc.subject.keywords |
spectroscopy |
|
dc.subject.keywords |
equilibrium |
|
dc.subject.keywords |
structures |
|
dc.relation.journal |
Inorganica Chimica Acta |
|