dc.contributor.author |
Milanesio, M |
|
dc.contributor.author |
Viterbo, D |
|
dc.contributor.author |
Ramirez-Ortiz, J |
|
dc.contributor.author |
Valdes-Martínez, J |
|
dc.contributor.author |
Hernández, RP |
|
dc.contributor.author |
Rodríguez, JD |
|
dc.date.accessioned |
2011-01-22T10:27:31Z |
|
dc.date.available |
2011-01-22T10:27:31Z |
|
dc.date.issued |
2000 |
|
dc.identifier.issn |
0020-1693 |
|
dc.identifier.uri |
http://hdl.handle.net/11154/2589 |
|
dc.description.abstract |
(Salicylaldehyde-4-phenylthiosemicarbazidato) ammonium dioxovanadate(V), {1, NH4[VO2(PhSNO)]}, was synthesized and characterized by spectroscopic and magnetic measurements. Its crystal and molecular structure was determined by single-crystal X-ray diffraction which shows it to be the first example of a dioxovanadate(V) complex in which the vanadium is also linked to a sulfur atom. The PhSNO moiety is a bivalent, tridentate ligand. The V atom has the common square-pyramidal coordination geometry, which is compared with that found in other dioxovanadate(V) structures. The complex is linked to the NH4+ ion by a net of hydrogen bonds. (C) 2000 Elsevier Science S.A. All rights reserved. |
en_US |
dc.language.iso |
en |
en_US |
dc.title |
Synthesis, characterization and novel crystal structure of (salicylaldehyde-4-phenylthiosemicarbazidato) ammonium dioxovanadate(V) with a V-S bond |
en_US |
dc.type |
Article |
en_US |
dc.identifier.idprometeo |
2486 |
|
dc.source.novolpages |
306(1):125-129 |
|
dc.subject.wos |
Chemistry, Inorganic & Nuclear |
|
dc.description.index |
WoS: SCI, SSCI o AHCI |
|
dc.subject.keywords |
vanadium complexes |
|
dc.subject.keywords |
dioxo complexes |
|
dc.subject.keywords |
crystal structures |
|
dc.subject.keywords |
thiosemicarbazidato complexes |
|
dc.relation.journal |
Inorganica Chimica Acta |
|