dc.contributor.author |
Alvarez-Toledano, C |
|
dc.contributor.author |
Enriquez, J |
|
dc.contributor.author |
Toscano, RA |
|
dc.contributor.author |
Cortes-Cortes, E |
|
dc.contributor.author |
Osornio, YM |
|
dc.contributor.author |
Gutierrez-Perez, R |
|
dc.contributor.author |
Martínez-García, M |
|
dc.contributor.author |
García-Mellado, O |
|
dc.date.accessioned |
2011-01-22T10:27:42Z |
|
dc.date.available |
2011-01-22T10:27:42Z |
|
dc.date.issued |
1999 |
|
dc.identifier.issn |
0022-328X |
|
dc.identifier.uri |
http://hdl.handle.net/11154/2670 |
|
dc.description.abstract |
Diiron nonacarbonyl reacts with the para-substituted derivatives 1a-d of 3,3-dithio-1-(p-substituted phenyl)-2propen-1-one affording surprisingly the new dinuclear Fe(0) complexes 2a-d with a sigma-S coordination instead of the attended eta(2) or eta(4) pi-coordination upon the alpha,beta-unsaturated system of the ligands. The complexes 2a-c were characterized by mass spectrometry, IR and H-1- and C-13-NMR spectroscopies and their structures were fully confirmed by single-crystal X-ray analysis. Such structural studies revealed as the main feature an ideal C-2v (mm(2)) symmetry with the carbonyl groups in an eclipsed configuration of the Se2Fe2(CO)(6) moiety. (C) 1999 Elsevier Science S.A. All rights reserved. |
en_US |
dc.language.iso |
en |
en_US |
dc.title |
Synthesis and X-ray characterization of new 1-[mu-dithio-bis-(tricarbonyliron)]-2-(p-R-benzoyl)ethane complexes |
en_US |
dc.type |
Article |
en_US |
dc.identifier.idprometeo |
2702 |
|
dc.source.novolpages |
577(1):38-43 |
|
dc.subject.wos |
Chemistry, Inorganic & Nuclear |
|
dc.subject.wos |
Chemistry, Organic |
|
dc.description.index |
WoS: SCI, SSCI o AHCI |
|
dc.subject.keywords |
iron(0) |
|
dc.subject.keywords |
sulfur |
|
dc.subject.keywords |
dinuclear complexes |
|
dc.relation.journal |
Journal of Organometallic Chemistry |
|