dc.contributor.author |
GutierrezPerez, R |
|
dc.contributor.author |
Toscano, RA |
|
dc.contributor.author |
Cabrera, A |
|
dc.contributor.author |
GarcíaMellado, O |
|
dc.contributor.author |
Alvarez-Toledano, C |
|
dc.date.accessioned |
2011-01-22T10:27:56Z |
|
dc.date.available |
2011-01-22T10:27:56Z |
|
dc.date.issued |
1997 |
|
dc.identifier.issn |
0277-5387 |
|
dc.identifier.uri |
http://hdl.handle.net/11154/2868 |
|
dc.description.abstract |
The reaction between eta(4)-alpha,beta-unsaturated ketone-Fe(CO)(3) complexes and Me2CuLi in the absence of CO atmosphere yields the corresponding eta(4)-vinylketene complexes 2, 4 and 6. The reaction between eta(2)-dibenzylideneacetone-Fe(CO)(4) and Me2CuLi gives a new dimeric complex 8, which was characterized by mass spectrometry, IR, H-1 and C-13 NMR spectroscopy and its structure confirmed by single-crystal X-ray analysis. (C) 1997 Elsevier Science Ltd. |
en_US |
dc.language.iso |
en |
en_US |
dc.title |
Reaction of lithium dimethyl cuprate with carbonyl iron alpha,beta-unsaturated ketone complexes: The structure of a novel eta(3),eta(3)-[(1,6-diphenyl)-3,4-(distyr-1-yl)-1,3,5-hexatriene]-Fe(CO)(2) complex |
en_US |
dc.type |
Article |
en_US |
dc.identifier.idprometeo |
2971 |
|
dc.source.novolpages |
16(17):2979-2985 |
|
dc.subject.wos |
Chemistry, Inorganic & Nuclear |
|
dc.subject.wos |
Crystallography |
|
dc.description.index |
WoS: SCI, SSCI o AHCI |
|
dc.subject.keywords |
Me2CuLi |
|
dc.subject.keywords |
ketene |
|
dc.subject.keywords |
dimeric complex |
|
dc.subject.keywords |
iron(0) |
|
dc.relation.journal |
Polyhedron |
|