dc.contributor.author |
CeaOlivares, R |
|
dc.contributor.author |
Estrada, MR |
|
dc.contributor.author |
EspinosaPerez, G |
|
dc.contributor.author |
Haiduc, I |
|
dc.contributor.author |
CoteroVillegas, AM |
|
dc.contributor.author |
García, PGY |
|
dc.contributor.author |
LópezCardoso, M |
|
dc.contributor.author |
LópezVaca, M |
|
dc.date.accessioned |
2011-01-22T10:27:56Z |
|
dc.date.available |
2011-01-22T10:27:56Z |
|
dc.date.issued |
1995 |
|
dc.identifier.issn |
1024-1221 |
|
dc.identifier.uri |
http://hdl.handle.net/11154/2876 |
|
dc.description.abstract |
1-oxa-4,6-dithia-5-arsocane morpholinyldithiocarbamate (1) and 1,3,6-trithia-2-arsocane 2-diethyldithiocarbamate (2) have been prepared by reacting the corresponding sodium dithiocarbamates with 1-oxa-4,6-dithia-5-arsocane or 1,3,6-trithia-2-arsocane. (1) and (2) were characterized by elemental analyses, IR, MS, H-1 and C-13 NMR. The X-ray single-crystal molecular structures of (1) [monoclinic, a = 9.931(5), b = 18.253(5), c = 8.076(3) Angstrom |
en_US |
dc.description.abstract |
beta = 92.56(2)degrees |
en_US |
dc.description.abstract |
V = 1462.5(7) Angstrom(3) |
en_US |
dc.description.abstract |
space group P2(1)/c |
en_US |
dc.description.abstract |
Z = 4 |
en_US |
dc.description.abstract |
R = 4.33%] and (2) [monoclinic, a = 7.830(2), b = 10.465(2), c = 19.025(6) Angstrom |
en_US |
dc.description.abstract |
beta = 95.82(2)degrees |
en_US |
dc.description.abstract |
V = 1550.8(10) Angstrom(3) |
en_US |
dc.description.abstract |
space group P2(1)/c |
en_US |
dc.description.abstract |
Z = 4 |
en_US |
dc.description.abstract |
R = 3.41%], show that the compounds are monomeric and contain an asymmetric monometallic biconnective dithiocarbamate ligand with a large distortion in the geometry around the As and a weak heterocyclic arsocane transannular secondary interaction. |
en_US |
dc.language.iso |
en |
en_US |
dc.title |
1-oxa-4,6-dithia-5-arsocane and 1,3,6-trithia-2-arsocane dithiocarbamates competition between transannular and exocyclic secondary bonding to arsenic |
en_US |
dc.type |
Article |
en_US |
dc.identifier.idprometeo |
2986 |
|
dc.source.novolpages |
1(1):159-164 |
|
dc.subject.wos |
Chemistry, Multidisciplinary |
|
dc.description.index |
WoS: SCI, SSCI o AHCI |
|
dc.relation.journal |
Main Group Chemistry |
|